INDICE: Preface. Contributors. Dedication. Notice to Contributors and Checkers. Toxic Substances and Laboratory Hazards. Chapter One COMPLEXES OF BULKY ß-DIKETIMINATE LIGANDS. 1. Introduction. 2. ß-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl). 3. ß-Diketiminate Precursors LMe,iPr2H, [LMe,iPr2Li]x, and [LtBu,iPr2K]x (LMe,iPr2 = 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl; LtBu,iPr2 = 2,2,6,6- Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl). 4. ß-Diketiminate Precursors LtBu,iPr2H and LtBu,iPr2Li(THF) (LtBu,iPr2=2,2,6,6-Tetramethyl-3,5- Bis-(2,6-Diisopropylphenylimido)Heptyl). 5. Scandium Trichloride Tris(Tetrahydrofuran) and ß-Diketiminate-Supported Scandium Chloride Complexes. 6. ß-Diketiminate-Supported Titanium and Vanadium Dichloride Complexes. 7. ß-Diketiminate-Supported Vanadium and Chromium Chloride Complexes. 8. ß-Diketiminate-Supported Manganese and Zinc Complexes. 9. Iron 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2FeCl).10. Iron 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl Chloride (LtBu,iPr2FeCl). 11. Cobalt 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido) Heptyl Chloride (LtBu,iPr2CoCl). 12. ß-Diketiminate-Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl). 13. Nickel 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride Dimer, [LMe,iPr2Ni(µ-Cl)]2. 14. Bis[Copper 2,4-Bis-(2,4,6-Trimethylphenylimido)Pentyl] Toluene, (LMe,Me3Cu)2(µ-n2:n2-C7H8). 15. Copper 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2CuCl). Chapter Two BORON CLUSTER COMPOUNDS. 16. Salts of Dodecamethylcarba-closo-Dodecaborate() Anion, CB11Me12, and the Radical Dodecamethylcarba-closo-Dodecaboranyl, CB11Me12. 17. Cesium Dodecahydroxy-closo-Dodecaborate, Cs2[B12(OH)12]. Chapter Three COORDINATION COMPOUNDS. 18. Pentaaquanitrosylchromium Sulfate. 19. The Tetradentate Bispidine Ligand Dimethyl-(3,7-Dimethyl-9-oxo-2,4-bis(2-pyridyl)-3,7-Diazabicyclo[3.3.1]nonane)-1, 5-dicarboxylate and Its Copper(ll) Complex. 20. Tris(2-Picolinyl)Methane and ItsCopper(I) Complex. Chapter Four CARBENE LIGANDS AND COMPLEXES. 21. 1,3-Dialkyl-Imidazole-2-Ylidenes. 22. A Chelating Rhodium N-Heterocyclic Carbene Complexby Transmetallation from a SilverNHC Intermediate. 23. Rhodium and Iridium N-Heterocyclic Carbene Complexes from Imidazolium Carboxylates. Chapter Five FUNCTIONAL LIGANDS AND COMPLEXES. 24. N-tert-Butyl ortho-Aminophenol, ortho-Iminoquinone, and a Zirconium(IV) bis(Aminophenolate) Complex. 25. Synthesis of theWater-Soluble Bidentate (P, N) Ligand PTN(Me) (PTN(Me) = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane). 26. Synthesis of Metal-Organic Frameworks: MOF-5 and MOF-177. Chapter Six ORGANOMETALLIC REAGENTS. 27. Tricarbonyl 1,3,5-Trimethyl-1,3,5-Triazacyclohexane Complexes of Chromium(0), Molybdenum(0), and Tungsten(0) [M(CO)3(Me3TACH) (M = Cr, Mo, W)].%;
- ISBN: 978-0-471-68255-4
- Editorial: John Wiley & Sons
- Encuadernacion: Cartoné
- Páginas: 187
- Fecha Publicación: 15/10/2010
- Nº Volúmenes: 1
- Idioma: Inglés