Resolving Spectral Mixtures: With Applications from Ultrafast Time-Resolved Spectroscopy to Superresolution Imaging

Resolving Spectral Mixtures: With Applications from Ultrafast Time-Resolved Spectroscopy to Superresolution Imaging offers a comprehensive look into the most important models and frameworks essential to resolving the spectral unmixing problem-from multivariate curve resolution and multi-way analysis to Bayesian positive source separation and nonlinear unmixing. Unravelling total spectral data into the contributions from individual unknown components with limited prior information is a complex problem that has attracted continuous interest for almost four decades. Spectral unmixing is a topic of interest in statistics, chemometrics, signal processing, and image analysis. For decades, researchers from these fields were often unaware of the work in other disciplines due to their different scientific and technical backgrounds and interest in different objects or samples. This led to the development of quite different approaches to solving the same problem. This multi-authored book will bridge the gap between disciplines with contributions from a number of well-known and strongly active chemometric and signal processing research groups. Among chemists, multivariate curve resolution methods are preferred to extract information about the nature, amount, and location in time (process) and space (imaging and microscopy) of chemical constituents in complex samples. In signal processing, assumptions are usually around statistical independence of the extracted components. However, the chapters include the complexity of the spectral data to be unmixed as well as dimensionality and size of the data sets. Advanced spectroscopy is the key thread linking the different chapters. Applications cover a large part of the electromagnetic spectrum. Time-resolution ranges from femtosecond to second in process spectroscopy and spatial resolution covers the submicronic to macroscopic scale in hyperspectral imaging. Demonstrates how and why data analysis, signal processing, and chemometrics are essential to the spectral unmixing problemGuides the reader through the fundamentals and details of the different methodsPresents extensive plots, graphical representations, and illustrations to help readers understand the features of different techniques and to interpret resultsBridges the gap between disciplines with contributions from a number of well-known and highly active chemometric and signal processing research groups INDICE: 1. Introduction. Ways and means to deal with the spectral mixture problem 2. Multivariate curve resolution - alternating least squares 3. Spectral unmixing using the concept of pure variables 4. Ambiguities in multivariate curve resolution 5. Multivariate curve resolution of compressed data 6. Experimental and data analytical approaches to automating multivariate curve resolution in the analysis of hyperspectral images 7. Implementation of smoothness - roughness constraints in multivariate curve resolution - alternating least squares 8. Super-resolution in vibrational spectroscopy: from multiple low resolution images to high resolution images 9. Multivariate curve resolution for Magnetic Resonance Image analysis: applications in prostate cancer biomarkers development 10. Deconvolution of complex hyphenated chromatographic data with spectral detection 11. Analysis and resolution of ultrafast time-resolved spectroscopy data 12. Independent component analysis: theory and applications 13. Multiresolution analysis and chemometrics for pattern enhancement and resolution in spectral signals and images 14. Bayesian Positive Source Separation factorization of spectral mixtures 15. Linear and nonlinear unmixing in hyperspectral imaging 16. Endmember library approaches to resolve spectral mixing problems in remotely sensed data: challenges, potential and applications 17. Unmixing of hyperspectral image by taking into account spectral and spatial dimension of data 18. Sparse-based models and filter-based approaches on hyperspectral analysis

• ISBN: 978-0-444-63638-6
• Editorial: Elsevier
• Encuadernacion: Cartoné
• Páginas: 375
• Fecha Publicación: 01/09/2016
• Nº Volúmenes: 1
• Idioma: Inglés